Monomer |
Vmax or Vmin
|
Complex |
Vmin
|
ΔVmin
b
|
X…CN-Ph-CN |
X…CN-Ph-CN |
X…CN-Ph-CN |
X…CN-Ph-CN |
X…CN-Ph-CN |
|
|
CN-Ph-CN*
|
-32.23 |
0.00 |
F-F*
|
12.99
|
F2…CN-Ph-CN*
|
-31.65
|
0.58
|
Cl-Cl*
|
25.59
|
Cl2…CN-Ph-CN*
|
-30.69
|
1.54
|
Br-Br*
|
30.76
|
Br2…CN-Ph-CN*
|
-30.15
|
2.09
|
F-Cl*
|
44.53
|
FCl…CN-Ph-CN*
|
-28.98
|
3.26
|
F-Br*
|
54.37
|
FBr…CN-Ph-CN*
|
-27.84
|
4.39
|
Br-Cl*
|
19.47
|
BrCl…CN-Ph-CN*
|
-31.26
|
0.97
|
Cl-Br*
|
36.94
|
ClBr…CN-Ph-CN*
|
-29.51
|
2.72
|
F*-CN
|
13.19
|
FCN…CN-Ph-CN*
|
-30.99
|
1.25
|
Cl*-CN
|
37.99
|
ClCN…CN-Ph-CN*
|
-29.81
|
2.42
|
Br*-CN
|
45.07
|
BrCN…CN-Ph-CN*
|
-29.14
|
3.10
|
B*H3
|
41.78
|
BH3…CN-Ph-CN*
|
-28.53
|
3.71
|
B*F3
|
53.35
|
BF3…CN-Ph-CN*
|
-26.02
|
6.22
|
Z…Br-Ph-CN |
Z…Br-Ph-CN |
Z…Br-Ph-CN |
Z…Br-Ph-CN |
Z…Br-Ph-CN |
|
|
Br-Ph-CN*
|
-36.54 |
0.00 |
N*H3
|
-40.44
|
NH3…Br-Ph-CN*
|
-39.63
|
-3.09
|
N*H2CH3
|
-38.52
|
NH2CH3…Br-Ph-CN*
|
-39.68
|
-3.14
|
N*H=CH2
|
-38.72
|
N*H=CH2…Br-Ph-CN*
|
-39.54
|
-3.00
|
HCN
|
-32.44
|
HCN…Br-Ph-CN*
|
-39.40
|
-2.85
|