Introduction: This case report describes the use of a PulseSelect™ catheter in a patient with atrial fibrillation (AF), using optimal fluoroscopic angulation to ensure tissue-catheter contact during pulsed field ablation (PFA). Methods and Results: A 51-year-old woman with paroxysmal AF underwent PFA using a PulseSelect™ catheter. Preprocedural cardiac computed tomography was used to identify the optimal fluoroscopic angulations for obtaining en face and perpendicular views for pulmonary vein isolation (PVI). Complete PVI was achieved, with no AF recurrence within a 3-month follow-up. Conclusion: This case demonstrates the feasibility of obtaining and applying optimal fluoroscopic angulation during PFA using the PulseSelect™.