Indoor exposure to airborne PAHs: A comparison of stir bar sorptive
extraction and pump sampling
Abstract
Stir bar sorptive extraction (SBSE) was compared with standardized pump
sampling regarding the prospects to assess airborne levels of polycyclic
aromatic hydrocarbons (PAHs) in indoor environments. A historic railway
water tower, which will be preserved aa technical monument for museum
purposes, was sampled with both approaches because built-in insulation
material was suspected to release PAHs to the indoor air. The 16 PAH on
the US EPA list were quantified using gas chromatography with mass
selection detection in filters from pump sampling after solvent
extraction and on SBSE devices after thermal desorption. SBSE was seen
to sample detectable PAH masses with excellent repeatability and a
congener pattern largely similar to that observed with pump sampling.
Congener patterns were however significantly different from that in the
PAH source because release from the insulation material is largely
triggered by the respective congener vapor pressures. Absolute masses in
the ng range sampled by SBSE corresponded to airborne concentrations in
the ng L -1 range determined by pump sampling. Principle differences
between SBSE and pump sampling as well as prospects of SBSE as
cost-effective and versatile complement of pump sampling are discussed.