Construction of Angularly Fused Tricyclic Compounds via Photo-induced
Radical Cascade Cyclization
- Mengqin Hu,
- Wei Cao,
- Yan Hao,
- Ganxing Huang,
- Yuqiao Zhou,
- Song Qin,
- Shaomin Fu,
- Bo Liu
Abstract
A photo-triggered cascade cyclization of silyl enolate to prepare
angularly fused tricyclic scaffold is developed. The reaction
demonstrates good substrate scope and stereo-selectivity. The excellent
stereo- and regio-selectivity for this cascade reaction is elucidated
via conformational analysis and DFT calculation, respectively.27 Apr 2023Reviewer(s) Assigned 19 May 2023Review(s) Completed, Editorial Evaluation Pending
22 May 2023Editorial Decision: Revise Minor
23 May 20231st Revision Received
24 May 2023Assigned to Editor
24 May 2023Submission Checks Completed
24 May 2023Review(s) Completed, Editorial Evaluation Pending
24 May 2023Editorial Decision: Accept