Abstract
A world record conversion efficiency of 26.81% has been achieved
recently by LONGi team on industry-grade silicon wafer (274 cm
2, M6 size). An unparalleled high fill factor (
FF) of up to 86.59% boosted the cell performance. The
theoretical FF limit has been predicted to be 89.26%, while the
practical FF is far below this limit for a prolonged interval due
to the constraints of recombination ( i.e., SRH recombination)
and series resistance. The ideality factor ( m) in the equivalent
circuit of silicon solar cells is consistently ranging from 1 to 2 and
rarely falls below 1, resulting in a relatively lower FF than
85%. Here, this work complements a systematic simulation study to
demonstrate how to approach the FF limit in silicon solar cell
fabrication. Firstly, a diode component with an ideality factor equal to
2/3 corresponding to Auger recombination is incorporated in the
equivalent circuit for LONGi’ ultra-high FF solar cell; Secondly,
an advanced equivalent circuit is put forward for comprehensive analysis
of bulk recombination and surface recombination on the performance, in
which specific ideality factors are directly correlated with various
recombination mechanisms exhibiting explicit reverse saturation current
density ( J 0); Finally, we evaluate precisely
the route for approaching theoretical FF in practical solar cell
fabrication based on electrical design parameters using the developed
model.