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Electrochemical Beckmann Rearrangement Mediated by DDQ
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  • Ren-Yu Tian,
  • Mohammad Haqmal,
  • Yu-Ting Bao,
  • Shi-Yao Liu,
  • Guangying Chen,
  • Li Tang
Ren-Yu Tian
Hainan Normal University
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Mohammad Haqmal
Hainan Normal University
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Yu-Ting Bao
Hainan Normal University
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Shi-Yao Liu
Hainan Normal University
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Guangying Chen
Hainan Normal University
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Li Tang
Hainan Normal University

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Abstract

Beckmann rearrangement, a classical reaction of introducing nitrogen to carbon skeleton compounds, is widely used in acadimia and industry. Herein, an electrochemical Beckmann rearrangement is reported, utilizing 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as a mediator to prevent the over-electro-oxidation of products, which could afford amide in excellent yield.
Submitted to Chinese Journal of Chemistry
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