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Impact of rapid thermal processing on bulk lifetime and surface recombination velocity of crystalline silicon with passivating tunnel oxide contacts
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  • Franz-Josef Haug,
  • Audrey Morisset,
  • M. Lehmann,
  • S. Libraro,
  • E. Genç,
  • Julien Hurni,
  • Christophe Ballif
Franz-Josef Haug
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory

Corresponding Author:[email protected]

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Audrey Morisset
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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M. Lehmann
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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S. Libraro
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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E. Genç
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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Julien Hurni
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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Christophe Ballif
Ecole Polytechnique Federale de Lausanne Photovoltaics Laboratory
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Abstract

We investigate rapid thermal processing (RTP) as alternative to the prolonged thermal annealing process used to form tunnel-oxide passivating contacts for silicon solar cells. The thermal treatment is generally followed by hydrogenation to passivate defects at the Si/SiOx interface. Whereas industrial manufacturing generally uses Cz wafers, research is often carried out with FZ wafers. Both types of wafers are prone to the formation of thermal defects in the bulk. To disentangle effects of the interface and the bulk, we assess the lifetime at different steps of the process sequence for both wafer types. We find that the initial bulk lifetime of our p-type FZ material is maintained for RTP up to temperatures of about 450°C, followed by a severe decay and eventually a moderate extent of recovery at temperatures above 800°C. Compared to FZ material, the initial bulk lifetimes in our p-type Cz material are slightly lower, but they are maintained on that level up to about 600°C. Beyond that temperature, the lifetimes also decay, but to a lesser extent than in the FZ material, and there is no curing at higher temperatures. Hydrogenation can partially passivate the bulk defects in FZ material, but the initial state is not recovered. In Cz material, it appears that RTP creates two different types of defects; for those created up to 800°C the initial state can be recovered by hydrogenation whereas those created at higher temperature cannot be passivated by hydrogenation. We also investigate the formation of n-type passivating contacts by RTP, and we fabricate solar cell precursors with a single RTP step and the same hydrogenation for both contact polarities. After sputtering a transparent conducting ITO layer on the full area and an Ag metallization, we achieve solar cells efficiencies up to 20.5%.
Submitted to Progress in Photovoltaics
Submission Checks Completed
Assigned to Editor
Reviewer(s) Assigned
17 Jul 2024Reviewer(s) Assigned
03 Sep 2024Review(s) Completed, Editorial Evaluation Pending
03 Sep 2024Editorial Decision: Revise Minor
19 Sep 20241st Revision Received
25 Sep 2024Submission Checks Completed
25 Sep 2024Assigned to Editor
25 Sep 2024Review(s) Completed, Editorial Evaluation Pending
21 Oct 2024Reviewer(s) Assigned
18 Nov 2024Editorial Decision: Revise Minor
21 Nov 20242nd Revision Received
21 Nov 2024Submission Checks Completed
21 Nov 2024Assigned to Editor
21 Nov 2024Review(s) Completed, Editorial Evaluation Pending