The vertical opacity structure of the martian atmosphere is important for understanding the distribution of ice (water and carbon dioxide) and dust. We present a new dataset of extinction opacity profiles from the NOMAD/UVIS spectrometer aboard the ExoMars Trace Gas Orbiter, covering one and a half Mars Years (MY) including the MY 34 Global Dust Storm and several regional dust storms. We discuss specific mesospheric cloud features and compare with existing literature and a Mars Global Climate Model (MGCM) run with data assimilation. Mesospheric opacity features, interpreted to be water ice, were present during the global and regional dust events and correlate with an elevated hygropause in the MGCM, providing further evidence for the role of regional dust storms in driving atmospheric escape as reported elsewhere. The season of the dust storms also had an apparent impact on the resulting lifetime of the cloud features, with events earlier in the dusty season correlating with longer-lasting mesospheric cloud layers. Mesospheric opacity features were also present during the dusty season even in the absence of regional dust storms, and interpreted to be water ice based on previous literature. The assimilated MGCM temperature structure agreed well with the UVIS opacities, but the MGCM opacity field struggled to reproduce mesospheric ice features, suggesting a need for further development of water ice parameterizations. The UVIS opacity dataset offers opportunities for further research into the vertical aerosol structure of the martian atmosphere, and for validation of how this is represented in numerical models.

Lower atmosphere variations in the martian water vapour and hydrogen abundance during the Mars Year (MY) 34 C storm from LS=326.1◦-333.5◦ and their associated effect on hydrogen escape are investigated using a multi-spacecraft assimilation of atmospheric retrievals into a Martian global circulation model. Elevation of the hygropause and associated increase in middle atmosphere hydrogen at the peak of the MY 34 C storm led to a hydrogen escape rate of around 1.4×109 cm−2s−1 , meaning the MY 34 C storm enhanced water loss rates on Mars to levels observed during global-scale dust storms. The water loss rate during the MY 34 C storm (a loss of 15% of the total annual water loss during only 5% of the year) was three times stronger than the weak MY 30 C storm assimilation, demonstrating that interannual variations in C storm strength must be considered when calculating the integrated loss of water on Mars.

The Europlanet H2020 program started on 1/9/2015 for 4 years. It includes an activity to adapt Virtual Observatory (VO) techniques to Planetary Science data called VESPA. The objective is to facilitate searches in big archives as well as sparse databases, to provide simple data access and on-line visualization, and to allow small data providers to make their data available in an interoperable environment with minimum effort. The VESPA system has been hugely improved during the first three years of Europlanet H2020: the infrastructure has been upgraded to describe data in many fields more accurately; the main user search interface (http://vespa.obspm.fr) has been redesigned to provide more flexibility; alternative ways to access Planetary Science data services from VO tools have been implemented; VO tools are being improved to handle specificities of Solar System data, e.g. measurements in reflected light, coordinate systems, etc. Current steps include the development of a connection between the VO world and GIS tools, and integration of Heliophysics, planetary plasmas, and mineral spectroscopy data to support of the analysis of observations. Existing data services have been updated, and new ones have been designed. The global objective is already overstepped, with 42 services open (including ESA’s PSA) and ~15 more being finalized. A procedure to install data services has been documented, and hands-on sessions are organized twice a year at EGU and EPSC; this is intended to favour the installation of services by individual research teams, e.g. to distribute derived data related to a published study. In complement, regular discussions are held with big data providers, starting with space agencies (IPDA). Common projects with PDS have been engaged, with the goal to connect PDS4 and EPN-TAP based on a local data dictionary. In parallel, a Solar System Interest Group has been established in IVOA; the goal is here to adapt existing astronomy standards to Planetary Science. The Europlanet 2020 Research Infrastructure project has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 654208. [1] Erard et al 2014, Astronomy & Computing 7-8, 71-80. http://arxiv.org/abs/1407.4886

We show a positive vertical correlation between ozone and water ice using a vertical cross-correlation analysis with observations from the ExoMars Trace Gas Orbiter’s NOMAD instrument. We find this is particularly apparent during the first half of Mars Year 35 (LS=0-180) at high southern latitudes, when the water vapour abundance is low. This contradicts the current understanding that ozone and water are, in general, anti-correlated. However, our simulations with gas-phase-only chemistry using a 1-D model show that ozone concentration is not influenced by water ice. Heterogeneous chemistry has been proposed as a mechanism to explain the underprediction of ozone in global climate models (GCMs) through the removal of HOX. We find improving the heterogeneous chemical scheme causes ozone abundance to increase when water ice is present, better matching observed trends. When water vapour abundance is high, there is no consistent vertical correlation between observed ozone and water ice and, in simulated scenarios, the heterogeneous chemistry does not have a large influence on ozone. HOX, which are by-products of water vapour, dominate ozone abundance and mask the effects of heterogeneous chemistry on ozone. This is consistent with gas-phase-only modelled ozone, showing good agreement with observations when water vapour is abundant. High water vapour abundance masks the effect of heterogeneous reactions on ozone abundance and makes adsorption of HOX have a negligible impact on ozone. Overall, the inclusion of heterogeneous chemistry improves the ozone vertical structure in regions of low water vapour abundance, which may partially explain GCM ozone deficits.

We present ~1.5 Mars Years (MY) of ozone vertical profiles, covering Ls = 163deg; in MY34 to Ls = 320deg; in MY35, a period which includes the 2018 global dust storm. Since April 2018, the Ultraviolet and Visible Spectrometer (UVIS) channel of the Nadir and Occultation for Mars Discovery (NOMAD) spectrometer aboard the ExoMars Trace Gas Orbiter has observed the vertical, latitudinal and seasonal distributions of ozone. Around perihelion, the relative abundance of ozone (and water from coincident NOMAD measurements) increases strongly together below ~40 km. Around aphelion, decreases in ozone abundance exist between 25-35 km coincident with the location of modelled peak water abundances. We report high latitude (above 55deg;), high altitude (40-55 km) equinoctial ozone enhancements in both hemispheres. The northern equinoctial high altitude enhancement is previously unobserved and forms prior to vernal equinox lasting for almost 100 sols (Ls ~350‑40deg), whereas the southern enhancement persists for over twice as long (Ls = ~5-140deg;). Both layers reform at autumnal equinox, with the northern layer at a lower abundance. These layers likely form through a combination of anti-correlation with water and the equinoctial meridional transport of O and H atoms to high-latitude regions. The descending branch of the main Hadley cell shapes the ozone distribution at Ls = 40-60deg;, with the possible signature of a northern hemisphere thermally indirect cell identifiable from Ls = 40-80deg;. The ozone retrievals presented here provide the most complete global description of Mars ozone vertical distributions as a function of season and latitude.

Solar occultations performed by the Nadir and Occultation for MArs Discovery (NOMAD) ultraviolet and visible spectrometer (UVIS) onboard the ExoMars Trace Gas Orbiter (TGO) have provided a comprehensive mapping of ozone density, describing the seasonal and spatial distribution of atmospheric ozone in detail. The observations presented here extend over a full Mars year between April 2018 at the beginning of the TGO science operations during late northern summer on Mars (Ls = 163°) and March 2020. UVIS provided transmittance spectra of the martian atmosphere in the 200 - 650 nm wavelength range, allowing measurements of the vertical distribution of the ozone density using its Hartley absorption band (200 – 300 nm). Our findings indicate the presence of (1) a high-altitude peak of ozone between 40 and 60 km in altitude over the north polar latitudes for over 45 % of the martian year, particularly during mid-northern spring, late northern summer-early southern spring, and late southern summer, and (2) a second, but more prominent, high-altitude ozone peak in the south polar latitudes, lasting for over 60 % of the year including the southern autumn and winter seasons. When they are present, both high-altitude peaks are observed in the sunrise and sunset occultations, indicating that the layers could persist during the day. Model results from the GEM-Mars General Circulation predicts the general behavior of the high-altitude peaks of ozone observed by UVIS and are used in an attempt to further our understanding of the chemical processes controlling the high-altitude ozone on Mars.