The Mars2020 Perseverance rover introduced Raman spectroscopy to in-situ planetary exploration for the first time when it landed in Jezero crater on Mars in February 2021. The SuperCam instrument onboard Perseverance is a multi-analytical tool capable of acquiring time-resolved Raman data from Martian targets at standoff distances of a few meters. This is a particularly challenging task due to the operational constraints, the harsh conditions on the Martian surface, and especially the very fine-grained nature of the Martian samples. To address these challenges, the SuperCam Raman team has invested significant effort into optimizing both the acquisition and post-processing of Raman data collected on Mars, as detailed in this work. Additionally, this paper reviews and discusses the detections made by SuperCam Raman during the first 1000 sols (almost 3 Earth years) of the Mars2020 mission. During this period, SuperCam Raman data provided key insights into the mineralogy of Jezero throughout the Crater, Delta, and Margin Campaigns. Key detections include olivine, carbonates, perchlorates, and sulfates (such as anhydrite), identified in both abraded patches and natural surfaces. The high specificity of Raman spectroscopy enables the unequivocal identification of these minerals, allowing for rapid and direct interpretation of Jezero’s mineralogy, especially when combined with other techniques from SuperCam or others on the rover. Furthermore, this paper compiles, reviews, and discusses the spectra acquired from the SuperCam Calibration Target (SCCT) samples on Mars, including studies on the degradation of the ertalyte organic sample and analyses of diamond, apatite, and other reference materials.

This paper introduces the basics of asymmetrical spectral band fitting and discusses the resolution of overlapping Gaussian shapes. We study how to fit overlapping bands with asymmetric Gaussian shapes. First, we derive an equation for an Asymmetric Gaussian shape. We then use this equation to derive a resolvability basis for the resolution of two nearby Gaussian bands. The so called Master Equation is then used to fit these two overlapping bands. We identify regions of the fitting space where the Asymmetric Gaussian fit is likely to be Optimal, Sub Optimal and Not Optimal. We then demonstrate the use of the Asymmetric Gaussian to fit four overlapping bands, and show how this is relevant to the olivine spectral complex at 1 μm. The limitations of the asymmetric band fitting method and a critical assessment of three commonly used numerical minimization and fitting methods are also provided.

We have studied the properties of the Nili Fossae olivine lithology from orbital data and in situ by the Mars 2020 rover at the Séítah unit in Jezero crater. We used the geochemistry collected by the rover’s instruments to calculate the viscosity and relative flow distance of the Séítah unit. Based on the low viscosity and distribution of the unit we postulate a ponded lava flow origin for the olivine rich unit at Séítah. We calculate an approximate depth for the cumulate layer of the lava pond based on the viscosity of the unit and model of Worster et al. (1993). We show that the resolution of orbital data is inadequate to map the phyllosilicate 2.38 μm band and demonstrate that it can be supplemented by in situ data from Mars 2020 SuperCam Laser Induced Breakdown Spectroscopy (LIBS) and reflectance observations to show that the low Al phyllosilicate in the olivine cumulate in the Séítah formation is either talc, serpentine, hectorite, Fe/Mg smectite, saponite or stevensite. We discuss two intertwining aspects of the history of the lithology: 1) the potential emplacement and properties of the cumulate layer within a ponded lava flow, using previously published models of ponded lava flows and lava lakes, and 2) the limited extent of post emplacement alteration, including phyllosilicate and carbonate alteration.

During the NASA Perseverance rover’s exploration of the Jezero crater floor, purple-hued coatings were commonly observed on rocks. These features likely record past water-rock-atmosphere interactions on the crater floor, and understanding their origin is important for constraining timing of water activity and habitability at Jezero. Here we characterize the morphologic, chemical, and spectral properties of the crater floor rock coatings using color images, visible/near-infrared reflectance spectra, and chemical data from the Mastcam-Z and SuperCam instruments. We show that coatings are common and compositionally similar across the crater floor, and consistent with a mixture of dust, fine regolith, sulfates, and ferric oxides indurated as a result of one or more episodes of widespread surface alteration. All coatings exhibit a similar smooth homogenous surface with variable thickness, color, and spatial extent on rocks, likely reflecting variable oxidation and erosional expressions related to formation and/or exposure age. Coatings unconformably overlie eroded natural rock surfaces, suggesting relatively late deposition that may represent one of the last aqueous episodes on the Jezero crater floor. While more common at Jezero, these coatings may be consistent with rock coatings previously observed in-situ at other landing sites and may be related to duricrust formation, suggesting a global alteration process on Mars that is not unique to Jezero. The Perseverance rover likely sampled these rock coatings on the crater floor and results from this study could provide important context for future investigations by the Mars Sample Return mission aimed at constraining the geologic and aqueous history of Jezero crater.

We have studied the observed properties of the Nili Fossae olivine-phyllosilicate-carbonate lithology from orbital data and in situ by the Mars 2020 rover at the Séítah unit in Jezero crater, including: 1) composition 2) grain size 3) inferred viscosity (calculated based on geochemistry collected by SuperCam (Wiens et al., 2022)). Based on the low viscosity and distribution of the unit we postulate a flood lava origin for the olivine-phyllosilicate-carbonate at Séítah. We include a new CRISM map of the phyllosilicate 2.38 μm band and use in situ data from Mars 2020 SuperCam Laser Induced Breakdown Spectroscopy (LIBS) and VISIR and MastCam-Z observations to show that the phyllosilicate in the olivine cumulate in the Séítah formation is either talc, serpentine, hectorite, Fe/Mg smectite, saponite or stevensite. We discuss two intertwining aspects of the history of the lithology: 1) the emplacement and properties of the cumulate layer within a lava lake, based on terrestrial analogs in the Pilbara, Western Australia, and using previously published models of flood lavas and lava lakes, and 2) the limited extent of post emplacement alteration, including phyllosilicate and carbonate alteration.

The first samples collected by the Perseverance rover on the Mars 2020 mission were from the Maaz formation, a lava plain that covers most of the floor of Jezero crater. Laboratory analysis of these samples back on Earth will provide important constraints on the petrologic history, aqueous processes, and timing of key events in Jezero. However, interpreting these samples will require a detailed understanding of the emplacement and modification history of the Maaz formation. Here we synthesize rover and orbital remote sensing data to link outcrop-scale interpretations to the broader history of the crater, including Mastcam-Z mosaics and multispectral images, SuperCam chemistry and reflectance point spectra, RIMFAX ground penetrating radar, and orbital hyperspectral reflectance and high-resolution images. We show that the Maaz formation is composed of a series of distinct members corresponding to basaltic to basaltic andesite lava flows. The members exhibit variable spectral signatures dominated by high-Ca pyroxene, Fe-bearing feldspar, and hematite, which can be tied directly to igneous grains and altered matrix in abrasion patches. Spectral variations correlate with morphological variations, from recessive layers that produce a regolith lag in lower Maaz, to weathered polygonally fractured paleosurfaces and crater-retaining massive blocky hummocks in upper Maaz. The Maaz members were likely separated by one or more extended periods of time, and were subjected to variable erosion, burial, exhumation, weathering, and tectonic modification. The two unique samples from the Maaz formation are representative of this diversity, and together will provide an important geochronological framework for the history of Jezero crater.

Observations by several cameras on the Perseverance rover showed a 22° scattering halo around the Sun over several hours on the morning of sol 292 (15 December 2021). Such a halo has not previously been seen off Earth. The halo occurred during the aphelion cloud belt season and the cloudiest time yet observed from the Perseverance site. The halo required crystalline water-ice cloud particles in the form of hexagonal columns large enough for refraction to be significant, at least 11 µm in diameter and length. Near 44 km altitude, fall speeds would have been 0.3-1 m/s for the smallest allowed particles. Over the 3.3-hour duration of the halo, particles could have fallen 3-12 km, causing downward transport of water and dust. Halo-forming clouds are likely rare due to the high supersaturation of water that is required but may be more common in northern subtropical regions during mid-northern summer.

This paper discusses the mathematical aspects of band fitting and introduces the mathematics of the Asymmetric Gaussian shape and its tangent space for the first time. First, we derive an equation for an Asymmetric Gaussian shape. We then use this equation to derive a rule for the resolution of two Gaussian shaped bands. We then use the Asymmetrical Gaussian equation to derive a Master Equation to fit two overlapping bands. We identify regions of the fitting space where the Asymmetric Gaussian fit is optimal, sub optimal and not optimal. We then demonstrate the use of the Asymmetric Gaussian to fit four overlapping Gaussian bands, and show how this is relevant to the olivine spectral complex at 1 ?m. We develop a new model of the olivine family spectrum based on previous work by Runciman and Burns. The limitations of the asymmetric band fitting method and a critical assessment of three commonly used numerical minimization methods are also provided.

The Perseverance rover, Mars 2020 mission, landed on the surface of the Jezero Crater, on February, 18th 2021. This Martian crater is suspected to have hosted a paleolake as evidenced by the numerous detections of aqueously-altered phases and thus is a promising candidate for the search for past Martian life. The SuperCam instrument, elaborated by a consortium of American and European laboratories, plays a leading role in this investigation thanks to its highly versatile payload providing rapid, synergistic, fine-scale mineralogy, chemistry, and color imaging. After its landing, the first measurements of Martian targets with the infrared spectrometer of SuperCam (IRS) showed new instrumental behaviors that had to be characterized and calibrated to derive unbiased science data. The IRS radiometric response has thus been calibrated using periodic observations of the Aluwhite SuperCam Calibration Target (SCCT). Parasitic effects were understood and mitigated, and the instrumental dark and noise are characterized and modeled. The reflectance calibrated data products, provided periodically on the NASA Planetary Data System, are corrected from the main instrumental features.

This paper exploits the Asymmetric Gaussian curve and its tangent space for the first time. We develop a new method of discriminating overlapping absorption bands. We then use the Asymmetrical Gaussian curve to derive a Master Equation to fit two overlapping bands. We then demonstrate the use of the Asymmetric Gaussian curve to fit four overlapping Gaussian bands, and show how this is relevant to the olivine family spectral complex at 1 μm. We report which olivine endmember is easiest to fit using an asymmetric curve. The limitations of the asymmetric band fitting method and a critical assessment of three commonly used numerical minimization methods are also provided.

We examine the observed properties of the Nili Fossae olivine-clay-carbonate lithology from orbital data and in situ by the Mars 2020 rover at the Séítah unit in Jezero crater, including: 1) composition (Liu, 2022) 2) grain size (Tice, 2022) 3) inferred viscosity (calculated based on geochemistry collected by SuperCam (Wiens, 2022)). Based on the low viscosity and distribution of the unit we postulate a flood lava origin for the olivine-clay-carbonate at Séítah. We include a new CRISM map of the clay 2.38 μm band and use in situ data to show that the clay in the olivine cumulate in the Séítah formation is consistent with talc or serpentine from Mars 2020 SuperCam LIBS and VISIR and MastCam-Z observations. We discuss two intertwining aspects of the history of the lithology: 1) the emplacement and properties of the cumulate layer within a lava lake, based on terrestrial analogs in the Pilbara, Western Australia, and using previously published models of flood lavas and lava lakes, and 2) the limited extent of post emplacement alteration, including clay and carbonate alteration (Clave, this issue; Mandon, this issue).

Perseverance landed at the Octavia E. Butler landing site next to the Séítah dune region in Jezero crater on 18 February 2021, in close proximity to the largest exposed carbonate deposit on Mars. These carbonate signatures have been shown to be associated with the strongest olivine signatures at Jezero crater (Goudge+ 2015, Brown+ 2020). Alteration of olivine can lead to carbonate+H2 production, an energy source for microbes (Mayhew+, 2013). The question of the origin of the olivine-carbonate unit represents both an opportunity and a challenge for the rover mission and future sample return efforts. Carbonate The landing site is not near the region of carbonate detections (Figure 1), however the rover’s westward traverse will take us over the carbonates on approach to the crater rim. No reliable indications of the 2.5 μm carbonate band have yet been convincingly detected by the SCAM VISIR instrument. Olivine Studies of the olivine-carbonate unit concluded the olivine is relatively Fe-rich and coarse grained (mm: Poulet+ 2007, Clenet+ 2013). The strongest in-situ olivine signatures are found in dune material analysed by LIBS/VISIR (Beyssac+ Mandon+ this conf). This grain size characterization work may be used to investigate the interaction of olivine with water and CO2 (Escamilla-Roa+ 2020). These surface-gas processes are enhanced when olivine is in fine grain form. Ash dispersal modeling is ongoing (Ravanis+ this conf) to determine the range different sized ash particles could have traveled on ancient Mars. We cannot directly compare the 1 μm band for CRISM and VISIR, so we developed a new method that measures the curvature of three points on the absorption bands to assess their relative Fo# shifts and applied it to both datasets. Lab spectroscopy will be used to assess spectral variations with composition versus grain size. Two key factors driving the Fo# are mantle composition and melt temperature. Brown+ (2020) estimated a range of Fo44-65 for the most redshifted olivine observed by CRISM. McGetchin+Smythe (1978) showed that an Fe-rich mantle composition would produce highly viscous lavas and suggested an upper bound of Fo70 for olivine. Understanding the astrobiological potential of the olivine-carbonate unit is a priority of M2020 (Farley+ 2020) and we will speculate on potential formation models in this contribution.