Low Earth Orbit (LEO) satellites are increasingly being used to provide connectivity for wide area Internet of Things (IoT) sensing applications. Since distributed IoT terminals are not able to coordinate their transmissions with each other to avoid packet collisions, Quality-of-Service (QoS) depends on the transmission attempt success statistics, which are time-varying. This paper presents asymptotic analysis results that characterize the IoT terminal's transmission attempt and success processes. We show that they converge to inhomogeneous Poisson processes, in the large population regime, and characterize the timedependent intensities as functions of the terminal locations and the attempt rate scheme. We also propose three terminal attempt rate schemes that are solutions to max-min optimization problems. The performance of the proposed schemes are compared in terms of individual terminal QoS as well as the populationwide QoS distribution. Performance for various IoT applications is also presented, using our asymptotic Poisson limit results.