The study aims to quantify the effect of Dufour number, on flow patterns and heat transfer rates in the exponentially accelerated vertical plate with MHD flow and chemical reaction. The unsteadiness of the flow suggests that time-dependent changes in velocity, temperature, and other relevant parameters are considered. MHD further complicates analysis with the electromagnetic interactions between the fluid and the field. The fluid, be characterized as a gray, absorbing/emitting radiation medium, indicating that it absorbs and emits thermal radiation but does not exhibit scattering behavior. Set of partial differential equations are then resolve using FEM. Graphical results are then discussed. Profiles vary with different, Dufour number, radiation, or temperature-dependent heat source/sink parameter. By varying the values of these governing parameters, on the skin-friction coefficient, Nusselt number, and Sherwood number are also analyzed.