Understanding the distribution of organic material, mineral inclusions, and porosity are critical to properly model the flow of fluids through rock formations in applications ranging from hydraulic fracturing and gas extraction, CO2 sequestration, geothermal power, and aquifer management. Typically, this information is obtained on the pore scale using destructive techniques such as focused ion beam scanning electron microscopy. Neutrons and X-rays provide non-destructive, complementary probes to gain three-dimensional distributions of porosity, minerals, and organic content along with fluid interactions in fractures and pore networks on the core scale. By capturing both neutron and X-ray tomography simultaneously it is possible to capture slowly dynamic or stochastic processes with both imaging modes. To facilitate this, NIST offers a system for simultaneous neutron and X-ray tomography at the Center for Neutron Research. This instrument provides neutron and X-ray beams capable of penetrating through pressure vessels to image the specimen inside at relevant geological conditions at resolutions ranging from 15 micrometers to 100 micrometers. This talk will discuss current efforts at identifying mineral and organic content and fracture and wettability in shales relevant to gas extraction.