Modulating the Electrolyte Inner Solvation Structure via Low Polarity
Cosolvent for Low-Temperature Aqueous Zinc-Ion Batteries
Abstract
Aqueous zinc-ion batteries (AZIBs) are regarded as the promising
candidates for large-scale energy storage systems owing to low cost and
high safety; however, their applications are restricted by their poor
low-temperature performance. Herein, a low-temperature electrolyte for
low-temperature AZIBs is designed by introducing low-polarity diglyme
(DGM) into an aqueous solution of Zn(ClO4)2. The DGM disrupts the
hydrogen-bonding network of water and lowers the freezing point of the
electrolyte to -105 °C. The designed electrolyte achieves ionic
conductivity up to 16.18 mS cm-1 at -45 °C. The DGM and ClO4-
reconfigure the solvated structure of Zn2+, which is more favorable for
the desolvation of Zn2+ at low temperatures. In addition, the DGM
effectively suppresses the dendrites, hydrogen evolution reaction, and
by-products of the zinc anode, improving the cycle stability of the
battery. At -20 °C, a Zn||Zn symmetrical cell is
cycled for 4,500 h at 1 mA cm-2 and 1 mA h cm-2, and a
Zn|| polyaniline (PANI) battery achieves an ultra-long
cycle life of 10,000 times. This study sheds light on the future design
of electrolytes with high ionic conductivity and easy desolvation at low
temperatures for rechargeable batteries.